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Researchers create new class of supplies known as ‘glass gels’

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Researchers have created a brand new class of supplies known as “glass gels” which can be simply as powerful as glassy polymers, however — in case you apply sufficient drive — can stretch as much as 5 instances their unique size, somewhat than break. The primary factor about glass gels is that they’re greater than 50% liquid, which makes them extra environment friendly at conducting electrical energy than widespread plastics which have related bodily properties. Credit score: Meixiang Wang, NC State College

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Researchers have created a brand new class of supplies known as “glass gels” which can be simply as powerful as glassy polymers, however — in case you apply sufficient drive — can stretch as much as 5 instances their unique size, somewhat than break. The primary factor about glass gels is that they’re greater than 50% liquid, which makes them extra environment friendly at conducting electrical energy than widespread plastics which have related bodily properties. Credit score: Meixiang Wang, NC State College

Researchers have created a brand new class of supplies known as “glass gels” which can be extraordinarily powerful and tough to interrupt regardless of containing greater than 50% liquid. Mixed with the truth that glassy gels are simple to supply, the fabric reveals promise for quite a lot of functions.

A paper describing this work is titled “Solvent-strengthened glass gels.” It seems Within the journal nature.

Glass gels and polymers are courses of supplies which have traditionally been considered as distinct from one another. Glass polymers are onerous, powerful, and sometimes brittle. They’re used to make issues like water bottles or airplane home windows. Gels, like contact lenses, include liquid and are tender and stretchy.

“We have created a category of supplies that we name glass gels, that are as inflexible as glassy polymers, however — in case you apply sufficient drive — can stretch as much as 5 instances their unique size, somewhat than break,” says Michael. Dickey, corresponding creator of a paper on the work and the Camille and Henry Dreyfus Professor of Chemical and Biomolecular Engineering at North Carolina State College. “What’s extra, as soon as the fabric is stretched, you possibly can return it to its unique form by making use of warmth. Moreover, the floor of glass gels is very adhesive, which is uncommon for stable supplies.”

“The primary factor about glass gels is that they’re greater than 50% liquid, which makes them extra environment friendly at conducting electrical energy than widespread plastics which have related bodily properties,” says Meixiang Wang, co-lead creator of the paper and a postdoctoral researcher. Researcher at North Carolina State. “Given the variety of distinctive properties they possess, we’re optimistic that these supplies might be helpful.”

Glass gels, as their identify suggests, are a cloth that mixes a number of the most engaging properties of each glass polymers and gels. To make them, researchers begin with liquid precursors of glassy polymers and blend them with an ionic liquid. This mixed liquid is poured right into a mildew and uncovered to UV mild, which causes the fabric to “treatment.” The mildew is then eliminated, forsaking the vitreous gel.


Credit score: Michael Dickey

“An ionic liquid is a solvent, like water, however composed completely of ions,” Dickey says. “Usually, when a solvent is added to a polymer, the solvent pushes the polymer chains aside, making the polymer tender and stretchy. Because of this moist contact lenses are versatile, whereas dry contact lenses should not. In glass gels, the solvent pushes the molecular chains in The polymer spreads aside from one another, permitting it to increase like a gel.

“Nevertheless, the ions within the solvent are strongly drawn to the polymer, stopping the polymer chains from shifting. The shortcoming of the chains to maneuver is what makes them glassy. The tip result’s that the fabric is stable because of the enticing forces, however remains to be in a position to stretch because of the additional distance.” “

The researchers discovered that cup gels could be made utilizing quite a lot of completely different polymers and ionic liquids, though not all courses of polymers can be utilized to create glass gels.

“Charged or polar polymers maintain promise for glassy gels, as a result of they’re drawn to the ionic liquid,” Dickey says.

extra data:
Michael Dickey, solvent strengthened glass gels, nature (2024). doi: 10.1038/s41586-024-07564-0. www.nature.com/articles/s41586-024-07564-0

Journal data:
nature


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